Blue sky

The blue color of the sky is caused by the scattering of sunlight off the molecules of the atmosphere. This scattering, called Rayleigh scattering, is more effective at short wavelengths (the blue end of the visible spectrum). Therefore the light scattered down to the earth at a large angle with respect to the direction of the sun's light is predominantly in the blue end of the spectrum.

Note that the blue of the sky is more saturated when you look further from the sun. The almost white scattering near the sun can be attributed to Mie scattering, which is not very wavelength dependent.

 
 

Pasted from <http://hyperphysics.phy-astr.gsu.edu/HBASE/atmos/blusky.html>